Search results for "Isobutyl alcohol"
showing 3 items of 3 documents
Phase equilibria in the systems isobutyl alcohol+N,N-dimethylformamide, isobutyl acetate+N,N-dimethylformamide and isobutyl alcohol+isobutyl acetate+…
2005
Abstract Consistent vapor–liquid equilibria (VLE) were determined for the ternary system isobutyl alcohol (IBA) + isobutyl acetate (IBAc) + N,N-dimethylformamide (DMF) and two constituent binary systems at 101.3 kPa. The IBA + DMF system exhibits negative deviation from ideal behaviour and IBAc + DMF system deviates positively from ideal behaviour. The activity coefficients of the solutions were correlated with its composition by the Wilson, NRTL and UNIQUAC models. The ternary system is well predicted from binary interaction parameters.
Separation of isobutyl alcohol and isobutyl acetate by extractive distillation and pressure-swing distillation: Simulation and optimization
2006
Abstract We have studied, simulated and evaluated economically two separation alternatives of a mixture made up of 52 mole% of isobutyl alcohol and 48 mole% of isobutyl acetate by means of a practical case of a plant to treat 12,000 Tm/year of the original mixture. The simulation has been carried out satisfactorily by means of a package of commercial software (Aspen HYSYS ® ) using the thermodynamic model UNIQUAC with binary parameters obtained experimentally by us. The two processes evaluated (extractive distillation using n -butyl propionate as a solvent and pressure-swing distillation) have been optimized independently from each other and the best configurations have been evaluated econo…